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Tritium ranged from −22 ± 13 to 96 ± 13 p Ci/L and δC values ranged from −15 to −11.2 ‰.No trends in the spatial distribution of physical and chemical parameters were apparent, although larger Sp C and ion concentrations were generally from groundwater in the southwestern part of the study area (Fig.Camas Creek is the primary source of surface water to Mud Lake and for most surface water irrigation in the study area; pumped groundwater is also used for irrigation.Infiltration recharge from surface water occurs from Medicine Lodge and Camas Creeks; ponds, lakes, and wetlands at Mud Lake and the CNWR; irrigation canals; and excess irrigation water (Spinazola Water-table contours indicate that groundwater flows into the ESRP aquifer from the Beaverhead Mountains and Camas Creek drainage basin and that groundwater generally flows south, southwest, or west (Fig. Hydraulic gradients calculated from water-table contours are relatively flat north of Mud Lake (approximately 0.5 m/km) and relatively steep in the northern part of the ESRP and south of Mud Lake (approximately 9.5 and 5.7 m/km, respectively).Large amounts of chloride, sodium, sulfate, and calcium are added to groundwater from irrigation water infiltrating through lake bed sediments containing evaporite deposits and the resultant dissolution of gypsum, halite, sylvite, and bischofite.), although proposed sources include solution of continuous fallout of Na Cl from the atmosphere, evaporation, infiltration of irrigation water, leaching of Na Cl from the soil horizon, solution of evaporite deposits, inputs of HCl and H, inflow of thermal water, flushing of grain boundaries and pores from marine sediments, dissolution of fluid inclusion Na Cl from basalt, and water–rock interaction with rhyolite and andesite (Robertson et al.Groundwater in the Mud Lake area resides in the eastern Snake River Plain (ESRP) aquifer, a sole-source fractured-basalt aquifer of significant economic value to the State of Idaho. The geochemical sources and processes controlling the water quality of groundwater of the Mud Lake area were determined by investigating the geology, hydrology, land use, and groundwater geochemistry in the Mud Lake area, proposing sources for solutes, and testing the proposed sources through geochemical modeling with PHREEQC (Parkhurst and Appelo ) are linear features on the ESRP that contain centers of basalt eruptions.Recharge to the Mud Lake area occurs from the Camas Creek and Medicine Lodge Creek drainage basins in the extreme northeastern extent of the aquifer, and groundwater in the aquifer flows downgradient (southwest) from the Mud Lake area through the Idaho National Laboratory (INL). Sediment in the ESRP is present at the surface and interbedded with basalt flows in the subsurface.

Wells include 20 irrigation, 12 domestic, and 1 stock, recreation, monitoring, and deep (geothermal) test well.Redox reactions, cation exchange, and evaporation were locally important.The source of large concentrations of chloride, sodium, sulfate, and calcium was evaporite deposits in the unsaturated zone associated with Pleistocene Lake Terreton.Nitrate concentrations were ≤0.25 mg/L as N (Table ).Thermal springs in the mountains (Lidy Hot Spring and Warm Spring, sites 57 and 58) were hot (48.4 and 27.8 °C), had low p H (7.2 and 7.1), and had Sp C of 694 and 430 µS/cm at 25 °C.

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